Combine flour, 2/3 cup sugar, 1/4 cup cocoa, coffee granules, baking powder, and salt in a bowl; stir well. Combine milk, oil, and vanilla in a bowl; add to dry ingredients, and stir well. Spoon batter into an 8-inch square baking pan coated with cooking spray. Combine remaining 1/3 cup sugar and remaining 2 tablespoons cocoa. Sprinkle over batter. Pour 1 cup boiling water over batter. (Do not stir.) Bake at 350° for 30 minutes or until cake springs back when lightly touched in center. Serve warm, topped with ice milk. Yield: 9 servings (serving size: 1 3x3-inch piece and 2 tablespoons ice milk). Calories 221 (25% from fat), protein,3.5g, Fat 6.1g (Sat 1.7g, Mono 1.6g, Poly 2.3g), Carb 38.2g, Fiber 0.4g, Chol 3mg, iron 1.3mg, Sodium 154mg, calcium 90mg) pc 146